To find the initial mass of \( \text{CO}_2 \), first calculate the number of moles corresponding to \( 10^{21} \) molecules.
Using Avogadro's number \( N_A = 6.02 \times 10^{23} \, \text{mol}^{-1} \):
\[ \frac{10^{21}}{6.02 \times 10^{23}} = 1.66 \times 10^{-3} \, \text{mol} \]
The initial moles of \( \text{CO}_2 \) are:
\[ 2.8 \times 10^{-3} + 1.66 \times 10^{-3} = 4.46 \times 10^{-3} \, \text{mol} \]
The molar mass of \( \text{CO}_2 \) is approximately \( 44 \, \text{g/mol} \).
Hence, the mass of \( \text{CO}_2 \) is:
\[ 4.46 \times 10^{-3} \, \text{mol} \times 44 \, \text{g/mol} = 196.24 \, \text{mg} \]
Thus, the initial mass of \( \text{CO}_2 \) is 196.2 mg.