A sample of $0.1\,g$ of water at $100^{\circ}C $ and normal pressure $(1.013 \times 10^5 \, Nm^{ -2})$ requires $54\,cal$ of heat energy to convert to steam at $100^{\circ}C $. If the volume of the steam produced is $167.1\, cc$, the change in internal energy of the sample, is