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Chemistry
List of top Chemistry Questions
The mass of carbon anode consumed (giving only carbondioxide) in the production of
$270\, kg$
of aluminium metal from bauxite by the Hall process is (Atomic mass
$Al =27$
)
JIPMER - 2007
JIPMER
Chemistry
General Principles and Processes of Isolation of Elements
Which one of the following compounds is most acidic?
JIPMER - 2007
JIPMER
Chemistry
Phenols
In a set of reactions, acetic acid yielded a product
$D$
. $CH _{3} COOH {->[{ SOCl _{2}}]}A {->[{\text { Benzene }}][{\text { anhyd. } AlCl _{3}} ]} B {->[{ HCN }]} C {->[{ HOH }]} D$ The structure of
$D$
would be
JIPMER - 2007
JIPMER
Chemistry
Aldehydes, Ketones and Carboxylic Acids
The amino acid which is not optically active is
KCET - 2007
KCET
Chemistry
Proteins
Ellingham diagram represents a graph of
KCET - 2007
KCET
Chemistry
General Principles and Processes of Isolation of Elements
Decomposition of benzene diozonium chloride by using
$Cu_2Cl_2/HCl$
to form chlorobenzene is
KCET - 2007
KCET
Chemistry
Amines
Benzene reacts with chlorine in sunlight to give a final product
KCET - 2007
KCET
Chemistry
Hydrocarbons
In which of the following molecules are all the bonds not equal?
NEET (UG) - 2006
NEET (UG)
Chemistry
Chemical bonding and molecular structure
The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH
3
(1.5 D) is larger than that of NF
3
(0.2 D). This is because:
NEET (UG) - 2006
NEET (UG)
Chemistry
Chemical bonding and molecular structure
The enthalpy of combustion of H
2
, cyclohexene (C
6
H
10
) and cyclohexene (C
6
H
12
) are -241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is:
NEET (UG) - 2006
NEET (UG)
Chemistry
Thermodynamics
Assume each reaction is carried out in an open container. For which reaction will ∆H = ∆E?
NEET (UG) - 2006
NEET (UG)
Chemistry
Thermodynamics
The enthalpy and entropy change for the reaction : Br
2
(l) + Cl
2
(g) → 2BrCl(g) are 30 kJ mol
-1
and 105 JK
-1
mol
-1
respectively. The temperature at which the reaction will be in equilibrium is :
NEET (UG) - 2006
NEET (UG)
Chemistry
Enthalpy change
More number of oxidation states are exhibited by the actinides than by the lanthanides. The main reason for this is:
NEET (UG) - 2006
NEET (UG)
Chemistry
d -and f -Block Elements
In which of the following pairs are both the ions coloured in aqueous solution? (Atomic number: Sc = 21, Ti = 22, Ni = 28, Cu = 29, Co = 27)
NEET (UG) - 2006
NEET (UG)
Chemistry
d -and f -Block Elements
Photochemical smog pollution does not contain:
NEET (UG) - 2006
NEET (UG)
Chemistry
Environmental Chemistry
[Cr(H
2
O)
6
]Cl
3
(at. no. of Cr = 24) has a magnetic moment of 3.83 BM, the correct distribution of 3d electrons in the chromium of the complex is:
NEET (UG) - 2006
NEET (UG)
Chemistry
coordination compounds
A hypothetical electrochemical cell is shown below
\(A|A+ (xM)|| B+ (yM)| B \)
The emf measured is +0.20 V. The cell reaction is:
NEET (UG) - 2006
NEET (UG)
Chemistry
Electrochemistry
If E°
Fe
2+
/Fe
= -0.441 V and E°
Fe
3+
/Fe
2+
= 0.771 V, the standard emf of the reaction: Fe + 2Fe
3+
\(→\)
3Fe
2+
will be:
NEET (UG) - 2006
NEET (UG)
Chemistry
Electrochemistry
During osmosis, flow of water through a semi-permeable membrane is :
NEET (UG) - 2006
NEET (UG)
Chemistry
Solutions
1.00 g of a non-electrolyte solute (molar mass 250 g mol
-1
) was dissolved in 51.2 g of benzene. If the freezing point depression constant, K
f
of benzene is 5.12 K kg mol
-1
, the freezing point of benzene will be lowered by:
NEET (UG) - 2006
NEET (UG)
Chemistry
Solutions
Self condensation of two moles of ethyl acetate in presence of sodium ethoxide yields:
NEET (UG) - 2006
NEET (UG)
Chemistry
Aldehydes, Ketones and Carboxylic Acids
A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of α-hydroxy acid. The carbonyl compound is:
NEET (UG) - 2006
NEET (UG)
Chemistry
Aldehydes, Ketones and Carboxylic Acids
Nucleophilic addition reaction will be most favoured in:
NEET (UG) - 2006
NEET (UG)
Chemistry
Aldehydes, Ketones and Carboxylic Acids
The general molecular formula, which represents the homologous series of alkanols is :
NEET (UG) - 2006
NEET (UG)
Chemistry
Hydrocarbons
A plot of
\(log\ \frac {x}{m}\)
versus
\(log \ p\)
for the adsorption of a gas on a solid gives a straight line with slope equal to:
NEET (UG) - 2006
NEET (UG)
Chemistry
Surface Chemistry
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