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Chemistry
List of top Chemistry Questions asked in AMUEEE
The
E
o
E^{o}
E
o
values of the following reduction reactions are given:
F
e
3
+
(
a
q
)
+
e
−
→
F
e
2
+
(
a
q
)
,
E
o
=
0.771
V
F e^{3+}(a q)+e^{-} \rightarrow F e^{2+}(a q), E^{o}=0.771\, V
F
e
3
+
(
a
q
)
+
e
−
→
F
e
2
+
(
a
q
)
,
E
o
=
0.771
V
F
e
2
+
(
a
q
)
+
2
e
−
→
F
e
(
s
)
,
E
o
=
−
0.447
V
F e^{2+}(a q)+2 e^{-} \rightarrow F e(s), E^{o}=-0.447\, V
F
e
2
+
(
a
q
)
+
2
e
−
→
F
e
(
s
)
,
E
o
=
−
0.447
V
What will be the free energy change for the reaction?
F
e
3
+
(
a
q
)
+
3
e
−
→
F
e
(
s
)
(
F
=
96485
C
m
o
l
−
1
)
Fe ^{3+}( aq )+3 e^{-} \rightarrow Fe ( s )\left( F =96485\, C\, mol ^{-1}\right)
F
e
3
+
(
a
q
)
+
3
e
−
→
F
e
(
s
)
(
F
=
96485
C
m
o
l
−
1
)
AMUEEE - 2012
AMUEEE
Chemistry
Gibbs Free Energy
The decomposition temperature is the lowest for
AMUEEE - 2012
AMUEEE
Chemistry
GROUP 2 ELEMENTS
Nitrogen base
+
+
+
Pentose sugar
+
+
+
Phosphate group is
AMUEEE - 2012
AMUEEE
Chemistry
Nucleic Acids
In
X
e
O
F
2
XeOF_{2}
X
e
O
F
2
molecule, the hybridisation of
X
e
Xe
X
e
orbitals is
AMUEEE - 2012
AMUEEE
Chemistry
p -Block Elements
Hydrolysis of proteins give
AMUEEE - 2012
AMUEEE
Chemistry
Biomolecules
Given that the radius of
N
a
+
N a^{+}
N
a
+
ion is
0.95
?
0.95 \,?
0.95
?
and that of
C
l
−
C l^{-}
C
l
−
ion is
1.81
?
1.81\,?
1.81
?
, hence in the close packed lattice of
C
l
−
Cl ^{-}
C
l
−
ions,
N
a
+
Na ^{+}
N
a
+
ions prefer to occupy
AMUEEE - 2012
AMUEEE
Chemistry
The solid state
Equivalent weight of potassium permanganate in alkaline solution is equal to
m
m
m
AMUEEE - 2012
AMUEEE
Chemistry
Redox reactions
Effective atomic number of the central metal ion,
P
t
Pt
Pt
, in the complex
[
P
t
(
N
H
3
)
6
]
4
+
\left[Pt\left(N H_{3}\right)_{6}\right]^{4+}
[
Pt
(
N
H
3
)
6
]
4
+
is: (The atomic no. of
P
t
Pt
Pt
is
78
78
78
)
AMUEEE - 2012
AMUEEE
Chemistry
coordination compounds
[
C
o
(
C
N
)
6
]
3
−
\left[C o(C N)_{6}\right]^{3-}
[
C
o
(
CN
)
6
]
3
−
, a complex ion of cobalt (III), absorbs radiations in violet region of the visible light. Its aqueous solution, therefore, appears
AMUEEE - 2012
AMUEEE
Chemistry
coordination compounds
C
l
?
O
Cl?O
Cl
?
O
bond order in perchlorate ion is
AMUEEE - 2012
AMUEEE
Chemistry
p -Block Elements
A solid has a structure in which, atoms of
W
,
O
W,O
W
,
O
and
N
a
Na
N
a
are located respectively at the comers, centre of edges and at the centre of the cubic lattice. The compound is
AMUEEE - 2012
AMUEEE
Chemistry
The solid state
Consider the cell,
P
t
∣
H
2
(
g
,
1
a
t
m
)
H
+
(
a
q
,
1
M
)
∥
F
e
3
+
(
a
q
)
P t \mid H_{2}(g, 1\, atm) H^{+}(a q, 1\, M) \| F e^{3+}(a q)
Pt
∣
H
2
(
g
,
1
a
t
m
)
H
+
(
a
q
,
1
M
)
∥
F
e
3
+
(
a
q
)
F
e
2
+
(
a
q
)
∣
P
t
(
s
)
F e^{2+}(a q) \mid P t(s)
F
e
2
+
(
a
q
)
∣
Pt
(
s
)
Given that
E
o
F
e
3
+
/
F
e
2
+
=
0.771
V
E^{o}{ }_{F e^{3+} / F e^{2+}}=0.771\, V
E
o
F
e
3
+
/
F
e
2
+
=
0.771
V
, the ratio of concentration of
F
e
(
a
q
)
2
+
F e_{(a q)}^{2+}
F
e
(
a
q
)
2
+
to
F
e
(
a
q
)
3
+
F e_{(a q)}^{3+}
F
e
(
a
q
)
3
+
is, when the cell potential is
0.830
V
0.830\, V
0.830
V
.
AMUEEE - 2012
AMUEEE
Chemistry
Electrochemistry
The gas that is adsorbed to a larger extent on charcoal is
AMUEEE - 2012
AMUEEE
Chemistry
Surface Chemistry
The main product of the reaction is
AMUEEE - 2012
AMUEEE
Chemistry
Hydrocarbons
The aldol condensation reaction is given by
AMUEEE - 2012
AMUEEE
Chemistry
Aldehydes, Ketones and Carboxylic Acids
To coagulate gelatin sol, which one of the following is most effective?
AMUEEE - 2012
AMUEEE
Chemistry
Surface Chemistry
Which will undergo
S
N
2
S _{ N } 2
S
N
2
reaction faster?
AMUEEE - 2012
AMUEEE
Chemistry
Haloalkanes and Haloarenes
Reaction of propene with diborane followed alkaline hydrolysis in the presence of hydrogen peroxide gives
AMUEEE - 2012
AMUEEE
Chemistry
Phenols
The hybridisation states of
[
N
i
(
C
O
)
4
]
[Ni(CO)_4]
[
N
i
(
CO
)
4
]
,
[
N
i
(
C
N
)
4
]
2
−
[Ni(CN)_4]^{2-}
[
N
i
(
CN
)
4
]
2
−
and
[
N
i
C
l
4
]
2
−
[NiCl_4]^{2-}
[
N
i
C
l
4
]
2
−
species are respectively
AMUEEE - 2011
AMUEEE
Chemistry
coordination compounds
Which of the following is not affected by the temperature?
AMUEEE - 2011
AMUEEE
Chemistry
Solutions
Heating of
N
H
4
N
O
3
NH _{4} NO _{3}
N
H
4
N
O
3
gives
AMUEEE - 2011
AMUEEE
Chemistry
p -Block Elements
The IUPAC name of the compound is
AMUEEE - 2011
AMUEEE
Chemistry
Organic Chemistry- Some Basic Principles and Techniques
Which of the following is an example of Maximum boiling azeotrope?
AMUEEE - 2011
AMUEEE
Chemistry
Solutions
The rate constant of a reaction is
mol
L
−
S
−
1
\text{mol} \,L^{-}\, S^{-1}
mol
L
−
S
−
1
. The reaction is
AMUEEE - 2011
AMUEEE
Chemistry
Chemical Kinetics
Le-Chatelier?s principle is not applicable to
AMUEEE - 2011
AMUEEE
Chemistry
Equilibrium
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