Step 1: Understand the concept of conservative forces and potential energy.
A force is said to be conservative if the work done by the force in moving a particle between two points is independent of the path taken. For a conservative force, it is possible to define a potential energy function \( U \) such that the force \( \vec{F} \) is related to the potential energy by \( \vec{F} = -\nabla U \) (in three dimensions) or \( F = -\frac{dU}{dx} \) (in one dimension). Equivalently, the work done by a conservative force over a closed path is zero.
Step 2: Analyze each of the given forces.
(1) Coulomb's force:
The electrostatic force between two charges is a conservative force. The work done by the Coulomb's force depends only on the initial and final positions of the charges, not on the path taken. The potential energy associated with the Coulomb's force is the electrostatic potential energy.
(2) Gravitational force:
The gravitational force between two masses is also a conservative force. The work done by the gravitational force depends only on the initial and final positions of the masses, and the potential energy associated with it is the gravitational potential energy.
(3) Frictional force:
Frictional force is a non-conservative force. The work done by friction depends on the path taken. For example, the work done against friction is greater along a longer path between two points. Also, the work done by friction over a closed path is not zero; it is always negative (dissipative).
Therefore, frictional force cannot be expressed in terms of a potential energy function. The energy dissipated by friction is converted into heat.
(4) Restoring force (e.g., spring force):
The restoring force exerted by a spring is a conservative force. The work done by the spring force depends only on the initial and final extensions or compressions of the spring, and the potential energy associated with it is the elastic potential energy.
Step 3: Identify the force that cannot be expressed in terms of potential energy.
Based on the analysis above, frictional force is a non-conservative force and cannot be expressed in terms of potential energy.