Which of the free radical is most stable?
- I
- II
- III
- IV
The Correct Option is C
Solution and Explanation
The stability of free radicals mirrors that of carbocations. Similar to carbocations, tertiary radicals exhibit greater stability compared to secondary and primary radicals. This phenomenon can be elucidated by the electron-donating (+I) effect of alkyl groups bonded to carbon radicals. As the number of alkyl groups attached to the carbon radical increases, there is a corresponding rise in the availability of electrons, leading to enhanced stabilization. Consequently, tertiary free radicals are more stabilized than secondary and primary counterparts.
The overall stability order among free radicals is:
triphenyl methyl > benzyl > allyl \(> 3^{\circ} > 2^{\circ} >1^{\circ} >\) methyl > vinyl.
So, the correct option is (C): III
Top Questions on Organic Chemistry- Some Basic Principles and Techniques
- The most stable carbocation among the following is:
- NEET (UG) - 2024
- Chemistry
- Organic Chemistry- Some Basic Principles and Techniques
- The compound that will undergo SN1 reaction with the fastest rate is
- NEET (UG) - 2024
- Chemistry
- Organic Chemistry- Some Basic Principles and Techniques
- Match List I with List II
List-I
(Conversion)List-II
(Shape/geometry)(A) 1 mol of H2O to O2 (I) 3F (B) 1 mol of MnO-4 to Mn2+ (II) 2F (C) 1.5 mol of Ca from molten CaCl2 (III) 1F (D) 1 mol of FeO to Fe2O3 (IV) 5F
Choose the correct answer from the options given below:- NEET (UG) - 2024
- Chemistry
- Organic Chemistry- Some Basic Principles and Techniques
- Given below are two statements :
Statement I : The boiling point of three isomeric pentanes follows the order
n-pentane > isopentane > neopentane
Statement II : When branching increases, the molecule attains a shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point.
In the light of the above statements, choose the most appropriate answer from the options given below :- NEET (UG) - 2024
- Chemistry
- Organic Chemistry- Some Basic Principles and Techniques
- Match List I with List II
List-I
(Complex)List-II
(Type of isomerism)(A) [Co(NH3)5(NO2)]Cl2 (I) Solvate isomerism (B) [Co(NH3)5(SO4)]Br (II) Linkage isomerism (C) [Co(NH3)6] [Cr(CN)6] (III) Ionization isomerism (D) [Co(H2O)6]Cl3 (IV) Coordination isomerism
Choose the correct answer from the options given below:- NEET (UG) - 2024
- Chemistry
- Organic Chemistry- Some Basic Principles and Techniques
Questions Asked in JEE Main exam
- In the given circuit if the power rating of Zener diode is 10 mW, the value of series resistance Rs to regulate the input unregulated supply is :
- JEE Main - 2024
- Zener Diodes
- 0.08 kg of air is heated at constant volume through 5°C. The specific heat of air at constant volume is 0.17 kcal/kg°C and \( J = 4.18 \) joule/cal. The change in its internal energy is approximately:
- JEE Main - 2024
- Thermodynamics
- \(^{n-1}C_r = (k^2 - 8) ^{n}C_{r+1}\) if and only if:
- JEE Main - 2024
- Binomial theorem
- If in a G.P. of64terms, the sum of all the terms is 7 times the sum of the odd terms of the G.P., then the common ratio of the G.P. is equal to:
- JEE Main - 2024
- Geometric Progression
- Match List-I with List-II
\[ \begin{array}{|c|c|} \hline \text{List-I (Species)} & \text{List-II (Electronic distribution)} \\ \hline \text{(A) Cr}^{+2} & \text{(I) } 3d^8 \\ \text{(B) Mn}^{+} & \text{(II) } 3d^3 4s^1 \\ \text{(C) Ni}^{+2} & \text{(III) } 3d^4 \\ \text{(D) V}^{+} & \text{(IV) } 3d^5 4s^1 \\ \hline \end{array} \]- JEE Main - 2024
- d And f - Block Elements
Concepts Used:
Organic Chemistry - Some Basic Principles and Techniques
Organic Chemistry is a subset of chemistry dealing with compounds of carbon. Therefore, we can say that Organic chemistry is the chemistry of carbon compounds and is 200-225 years old. Carbon forms bond with itself to form long chains of hydrocarbons, e.g.CH4, methane and CH3-CH3 ethane. Carbon has the ability to form carbon-carbon bonds quite elaborately. Polymers like polyethylene is a linear chain where hundreds of CH2 are linked together.
Read Also: Organic Compounds
Importance of Organic Chemistry:
Organic chemistry is applicable in a variety of areas including-
- Medicines: Example- Aspirin which is a headache medicine and Ibuprofen is a painkiller, both are organic compounds. Other examples include paracetamol.
- Food: Example- Starch which is a carbohydrate is an organic compound and a constituent of rice and other grains. It is the source of energy.
- Clothing: Example- Nylon, Polyester and Cotton are forms of organic compounds.
- Fuels: Examples- Gasoline, Petrol and Diesel are organic compounds used in the automobile industry at large.