Question:

Which of the following aqueous mixture is a buffer solution?

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Buffer solutions are created by mixing a weak acid with its conjugate base (or a weak base with its conjugate acid). In this case, acetic acid and sodium acetate form a buffer system.
Updated On: Mar 11, 2025
  • Acetic acid + Ammonium chloride
  • Hydrochloric acid + Potassium acetate
  • Acetic acid + Sodium chloride
  • Acetic acid + Sodium acetate
  • Sodium hydroxide + Potassium acetate
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The Correct Option is D

Solution and Explanation

A buffer solution consists of a weak acid and its conjugate base (or a weak base and its conjugate acid) in equilibrium. The purpose of the buffer is to maintain a relatively constant pH even when small amounts of an acid or base are added to the solution.
In this case, acetic acid is a weak acid and sodium acetate is the salt of the conjugate base of acetic acid (\( {CH}_3{COO}^- \)).
The mixture of acetic acid and sodium acetate forms a buffer solution because the acetic acid dissociates to produce \( {H}^+ \) and \( {CH}_3{COO}^- \), and the sodium acetate dissociates to produce \( {CH}_3{COO}^- \) and \( {Na}^+ \), thus maintaining the pH of the solution.
Therefore, the correct answer is (D) Acetic acid + Sodium acetate.
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