Plaster of Paris (\( \text{CaSO}_4 \cdot \frac{1}{2} \text{H}_2\text{O} \)) reacts with water to form Gypsum (\( \text{CaSO}_4 \cdot 2\text{H}_2\text{O} \)), a hard solid.
\[
\text{CaSO}_4 \cdot \frac{1}{2} \text{H}_2\text{O} + \frac{3}{2} \text{H}_2\text{O} \rightarrow \text{CaSO}_4 \cdot 2\text{H}_2\text{O}
\]