- The thermal decomposition reactions involve breaking down compounds into simpler products by heat.
- Reaction (ii) \( \text{CaCO}_3 \rightarrow \text{CaO} + \text{CO}_2 \) is a typical thermal decomposition reaction.
- Reaction (iv) \( 2 \, \text{KClO}_3 \rightarrow 2 \, \text{KCl} + 3 \, \text{O}_2 \) is also a thermal decomposition reaction.
Thus, the correct answer is (D).