In option (1), when milk is left open at room temperature, bacteria in the air may lead to fermentation, a chemical process.
In option (2), grapes undergo fermentation, which is a metabolic chemical reaction.
In option (3), when an iron nail is exposed to a humid atmosphere, it reacts with water and oxygen to form rust (iron oxide), a chemical reaction.
In option (4), the melting of glaciers is a physical change, not a chemical reaction, as there is no new substance formed.
Thus, the correct answer is option (4).
'संस्कृति' पाठ के आधार पर संस्कृति और असंस्कृति में अंतर बताइए।