To determine which gas will diffuse the fastest under identical conditions of temperature and pressure, we can use Graham's law of effusion. This law states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass (M). Mathematically, it can be expressed as:
Rate of effusion ∝ 1/√M
Let's compare the molar masses of the given gases:
- Oxygen (O2): Molar mass = 32 g/mol
- Nitrogen (N2): Molar mass = 28 g/mol
- Ammonia (NH3): Molar mass = 17 g/mol
- Hydrogen (H2): Molar mass = 2 g/mol
Since hydrogen (H2) has the smallest molar mass among the given options, according to Graham's law, it will diffuse the fastest.
Therefore, the correct answer is Hydrogen (H2).