




1. System A (Adiabatic System): In an adiabatic system, there is no heat exchange with the surroundings. During the combustion of methane, the heat generated cannot escape. This results in an increase in temperature within the system.
2. System B (Diathermic Container): In a diathermic container, heat can flow in and out of the system. During the combustion of methane, the heat generated escapes to maintain constant temperature.
Thus, in System A, the temperature rises, while in System B, the temperature remains the same.
Calculate the potential for half-cell containing 0.01 M K\(_2\)Cr\(_2\)O\(_7\)(aq), 0.01 M Cr\(^{3+}\)(aq), and 1.0 x 10\(^{-4}\) M H\(^+\)(aq).

The equivalent resistance between the points \(A\) and \(B\) in the given circuit is \[ \frac{x}{5}\,\Omega. \] Find the value of \(x\). 
Method used for separation of mixture of products (B and C) obtained in the following reaction is: 
In the following \(p\text{–}V\) diagram, the equation of state along the curved path is given by \[ (V-2)^2 = 4ap, \] where \(a\) is a constant. The total work done in the closed path is: 
Let \( ABC \) be a triangle. Consider four points \( p_1, p_2, p_3, p_4 \) on the side \( AB \), five points \( p_5, p_6, p_7, p_8, p_9 \) on the side \( BC \), and four points \( p_{10}, p_{11}, p_{12}, p_{13} \) on the side \( AC \). None of these points is a vertex of the triangle \( ABC \). Then the total number of pentagons that can be formed by taking all the vertices from the points \( p_1, p_2, \ldots, p_{13} \) is ___________.