The given pair of equations is:
\[
5x - ky = 2 \quad \text{(1)},
\]
\[
7x - 5y = 3 \quad \text{(2)}.
\]
We can represent this system of equations in matrix form as:
\[
\begin{pmatrix} 5 & -k \\ 7 & -5 \end{pmatrix} \begin{pmatrix} x \ y \e\nd{pmatrix} = \begin{pmatrix} 2 \\ 3 \end{pmatrix}.
\]
For the system to have a unique solution, the determinant of the coefficient matrix must be non-zero. The coefficient matrix is:
\[
A = \begin{pmatrix} 5 & -k \\ 7 & -5 \end{pmatrix}.
\]
The determinant of $A$ is given by:
\[
\text{det} = (5)(-5) - (7)(-k) = -25 + 7k.
\]
For a unique solution, we require:
\[
\text{det} \neq 0,
\]
which gives:
\[
-25 + 7k \neq 0,
\]
\[
7k \neq 25,
\]
\[
k \neq \frac{25}{7}.
\]
Thus, the value of $k$ for which the system has a unique solution is any value of $k$ except $\frac{25}{7}$.