In the Bohr model, the centripetal force required for an electron to revolve in a circular orbit is provided by the electrostatic force of attraction between the electron and the nucleus. The centripetal force is given by: \[ F_{\text{centripetal}} = \frac{m v^2}{r} \] where \( m \) is the mass of the electron, \( v \) is its speed, and \( r \) is the radius of the orbit. The electrostatic force is given by Coulomb's law: \[ F_{\text{electrostatic}} = \frac{k e^2}{r^2} \] where \( e \) is the charge of the electron, and \( k \) is Coulomb's constant. Equating these two forces: \[ \frac{m v^2}{r} = \frac{k e^2}{r^2} \] From this, we can solve for \( v \) and \( r \) in terms of \( n \), the principal quantum number. Using Bohr's quantization condition: \[ m v r = n h \quad \Rightarrow \quad v = \frac{n h}{2 \pi m r} \] Substitute \( v \) into the force equation: \[ \frac{m \left( \frac{n h}{2 \pi m r} \right)^2}{r} = \frac{k e^2}{r^2} \] Solving for \( r \) gives: \[ r \propto n^2 \] Now, the time period \( T \) is the time taken for one complete revolution, and it is related to the velocity \( v \) and the radius \( r \) by: \[ T = \frac{2 \pi r}{v} \] Substituting \( v \) and \( r \) into this equation: \[ T \propto n^3 \] Thus, the time period of revolution of the electron in the \( n \)-th orbit is proportional to \( n^3 \).
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]
Write chemical equations of the following reactions:
(i) Phenol is treated with conc. HNO\(_3\)
(ii) Propene is treated with B\(_2\)H\(_6\) followed by oxidation by H\(_2\)O\(_2\)/OH\(^-\)
(iii) Sodium t-butoxide is treated with CH\(_3\)Cl
Give a simple chemical test to distinguish between butan-1-ol and butan-2-ol.