According to quantum theory, the energy associated with a photon is given by
E = hf …(i)
Where
According to the mass-energy equivalence principle, the energy of a photon is
E = mc2 …(ii)
Where
From equation (i) and (ii), we have
hf = mc2
But frequency, f = c/λ
Where λ is wavelength
⇒ hc/λ = mc2
⇒ λ = h/mc
Instead of photon, we have material particle of mass m moving with velocity v, then
λ = h/mv
Where mv = p, momentum of the particle. Therefore
λ = h/p
Above expression is known as the expression for a de-Broglie wavelength that shows the wavelength associated with a particle of mass m moving with velocity v.
Given below are two statements:
Statement (I) : The dimensions of Planck’s constant and angular momentum are same.
Statement (II) : In Bohr’s model, electron revolves around the nucleus in those orbits for which angular momentum is an integral multiple of Planck’s constant.
In the light of the above statements, choose the most appropriate answer from the options given below:
If the system of equations \[ x + 2y - 3z = 2, \quad 2x + \lambda y + 5z = 5, \quad 14x + 3y + \mu z = 33 \] has infinitely many solutions, then \( \lambda + \mu \) is equal to:}
The equilibrium constant for decomposition of $ H_2O $ (g) $ H_2O(g) \rightleftharpoons H_2(g) + \frac{1}{2} O_2(g) \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $ is $ 8.0 \times 10^{-3} $ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($ \alpha $) of water is _____ $\times 10^{-2}$ (nearest integer value). [Assume $ \alpha $ is negligible with respect to 1]