According to quantum theory, the energy associated with a photon is given by
E = hf …(i)
Where
According to the mass-energy equivalence principle, the energy of a photon is
E = mc2 …(ii)
Where
From equation (i) and (ii), we have
hf = mc2
But frequency, f = c/λ
Where λ is wavelength
⇒ hc/λ = mc2
⇒ λ = h/mc
Instead of photon, we have material particle of mass m moving with velocity v, then
λ = h/mv
Where mv = p, momentum of the particle. Therefore
λ = h/p
Above expression is known as the expression for a de-Broglie wavelength that shows the wavelength associated with a particle of mass m moving with velocity v.
Given below are two statements:
Statement (I) : The dimensions of Planck’s constant and angular momentum are same.
Statement (II) : In Bohr’s model, electron revolves around the nucleus in those orbits for which angular momentum is an integral multiple of Planck’s constant.
In the light of the above statements, choose the most appropriate answer from the options given below:
A hydrogen atom consists of an electron revolving in a circular orbit of radius r with certain velocity v around a proton located at the nucleus of the atom. The electrostatic force of attraction between the revolving electron and the proton provides the requisite centripetal force to keep it in the orbit. According to Bohr’s model, an electron can revolve only in certain stable orbits. The angular momentum of the electron in these orbits is some integral multiple of \(\frac{h}{2π}\), where h is the Planck’s constant.
20 mL of sodium iodide solution gave 4.74 g silver iodide when treated with excess of silver nitrate solution. The molarity of the sodium iodide solution is _____ M. (Nearest Integer value) (Given : Na = 23, I = 127, Ag = 108, N = 14, O = 16 g mol$^{-1}$)