According to quantum theory, the energy associated with a photon is given by
E = hf …(i)
Where
According to the mass-energy equivalence principle, the energy of a photon is
E = mc2 …(ii)
Where
From equation (i) and (ii), we have
hf = mc2
But frequency, f = c/λ
Where λ is wavelength
⇒ hc/λ = mc2
⇒ λ = h/mc
Instead of photon, we have material particle of mass m moving with velocity v, then
λ = h/mv
Where mv = p, momentum of the particle. Therefore
λ = h/p
Above expression is known as the expression for a de-Broglie wavelength that shows the wavelength associated with a particle of mass m moving with velocity v.
Given below are two statements:
Statement (I) : The dimensions of Planck’s constant and angular momentum are same.
Statement (II) : In Bohr’s model, electron revolves around the nucleus in those orbits for which angular momentum is an integral multiple of Planck’s constant.
In the light of the above statements, choose the most appropriate answer from the options given below:
List I (Spectral Lines of Hydrogen for transitions from) | List II (Wavelength (nm)) | ||
A. | n2 = 3 to n1 = 2 | I. | 410.2 |
B. | n2 = 4 to n1 = 2 | II. | 434.1 |
C. | n2 = 5 to n1 = 2 | III. | 656.3 |
D. | n2 = 6 to n1 = 2 | IV. | 486.1 |
Match List-I with List-II: List-I