Two identical plates $ P $ and $ Q $, radiating as perfect black bodies, are kept in vacuum at constant absolute temperatures $ T_P $ and $ T_Q $, respectively, with $ T_Q<T_P $, as shown in Fig. 1. The radiated power transferred per unit area from $ P $ to $ Q $ is $ W_0 $. Subsequently, two more plates, identical to $ P $ and $ Q $, are introduced between $ P $ and $ Q $, as shown in Fig. 2. Assume that heat transfer takes place only between adjacent plates. If the power transferred per unit area in the direction from $ P $ to $ Q $ (Fig. 2) in the steady state is $ W_S $, then the ratio $ \dfrac{W_0}{W_S} $ is ____. 
Step 1: Power radiated between two black bodies
For two black bodies at temperatures \( T_P \) and \( T_Q \), the net power radiated per unit area is given by the Stefan-Boltzmann law:
\[ W = \sigma \left( T_P^4 - T_Q^4 \right) \]
So initially (Fig. 1), the power is:
\[ W_0 = \sigma \left( T_P^4 - T_Q^4 \right) \]
Step 2: Insert two intermediate black plates
In Fig. 2, two additional identical black plates are placed between \( P \) and \( Q \). Let the four plates be \( P, A, B, Q \) from left to right.
Assume steady state and let the temperatures of the intermediate plates be \( T_1 \) and \( T_2 \), such that:
\[ T_P>T_1>T_2>T_Q \]
Now, energy is transferred between adjacent pairs only:
At steady state, the energy flow rate must be the same through all three segments:
\[ \sigma (T_P^4 - T_1^4) = \sigma (T_1^4 - T_2^4) = \sigma (T_2^4 - T_Q^4) \]
Let this common value be \( W_S \), then:
\[ T_P^4 - T_1^4 = T_1^4 - T_2^4 = T_2^4 - T_Q^4 = \Delta \]
Therefore:
\[ \begin{align} T_P^4 - T_Q^4 &= (T_P^4 - T_1^4) + (T_1^4 - T_2^4) + (T_2^4 - T_Q^4) \\ &= 3\Delta = \frac{3W_S}{\sigma} \Rightarrow W_S = \dfrac{1}{3} \sigma (T_P^4 - T_Q^4) \end{align} \]
Step 3: Compute the ratio
\[ \frac{W_0}{W_S} = \frac{\sigma (T_P^4 - T_Q^4)}{(1/3) \sigma (T_P^4 - T_Q^4)} = \boxed{3} \]
Match List - I with List - II.

1.24 g of $ {AX}_2 $ (molar mass 124 g mol$^{-1}$) is dissolved in 1 kg of water to form a solution with boiling point of 100.105$^\circ$C, while 2.54 g of $ {AY}_2 $ (molar mass 250 g mol$^{-1}$) in 2 kg of water constitutes a solution with a boiling point of 100.026$^\circ$C. $ K_{b(H_2O)} = 0.52 \, \text{K kg mol}^{-1} $. Which of the following is correct?
For the reaction:

The correct order of set of reagents for the above conversion is :
The center of a disk of radius $ r $ and mass $ m $ is attached to a spring of spring constant $ k $, inside a ring of radius $ R>r $ as shown in the figure. The other end of the spring is attached on the periphery of the ring. Both the ring and the disk are in the same vertical plane. The disk can only roll along the inside periphery of the ring, without slipping. The spring can only be stretched or compressed along the periphery of the ring, following Hooke’s law. In equilibrium, the disk is at the bottom of the ring. Assuming small displacement of the disc, the time period of oscillation of center of mass of the disk is written as $ T = \frac{2\pi}{\omega} $. The correct expression for $ \omega $ is ( $ g $ is the acceleration due to gravity): 
Let $ a_0, a_1, ..., a_{23} $ be real numbers such that $$ \left(1 + \frac{2}{5}x \right)^{23} = \sum_{i=0}^{23} a_i x^i $$ for every real number $ x $. Let $ a_r $ be the largest among the numbers $ a_j $ for $ 0 \leq j \leq 23 $. Then the value of $ r $ is ________.