First, find the moles of ethanol required: \[ \text{Moles of ethanol} = M \times V = 0.25\, \text{mol/L} \times 3\, \text{L} = 0.75\, \text{mol} \] Now, calculate the mass of ethanol: \[ \text{Mass} = \text{moles} \times \text{molar mass} = 0.75 \times 60 = 45\, \text{g} \] Using the density formula, find the volume: \[ \text{Volume} = \frac{{\text{Mass}}}{{\text{Density}}} = \frac{45}{0.36} = 125\, \text{mL} \] Thus, the required volume of ethanol is 125 mL.