To determine the total number of sigma (\(\sigma\)) and pi (\(\pi\)) bonds in 2-oxohex-4-ynoic acid, analyze the structure:
\[\text{HO-CH}_2 - \text{C(=O)} - \text{CH}_2 - \text{C} \equiv \text{C} - \text{CH}_3\]
Count the sigma bonds (\(\sigma\)-bonds):
\(6 \, \sigma\)-bonds in carbon-hydrogen (C-H) bonds.
\(5 \, \sigma\)-bonds in carbon-carbon (C-C) single bonds.
\(2 \, \sigma\)-bonds in carbon-oxygen (C=O and C-O) bonds.
\(1 \, \sigma\)-bond in the hydroxyl (O-H) group.
Total \(\sigma\)-bonds: \(6 + 5 + 2 + 1 = 14\)
Count the pi bonds (\(\pi\)-bonds):
\(1 \, \pi\)-bond in the C=O bond.
\(3 \, \pi\)-bonds in the C \(\equiv\) C triple bond (\(2 \, \pi\)-bonds in the triple bond).
Total \(\pi\)-bonds: \(1 + 3 = 4\)
Therefore, the total number of bonds (sigma and pi) is:
\[14 + 4 = 18\]
What is the empirical formula of a compound containing 40% sulfur and 60% oxygen by mass?
Given below are two statements :
Statement I : Wet cotton clothes made of cellulose based carbohydrate takes comparatively longer time to get dried than wet nylon polymer based clothes.
Statement II : Intermolecular hydrogen bonding with water molecule is more in nylon-based clothes than in the case of cotton clothes.
In the light of the above statements, choose the Correct answer from the options given below
Match the LIST-I with LIST-II
LIST-I | LIST-II |
---|---|
A. PF5 | I. dsp2 |
B. SF6 | II. sp3d |
C. Ni(CO)4 | III. sp3d2 |
D. [PtCl4]2- | IV. sp3 |
Choose the correct answer from the options given below:
Match List-I with List-II: List-I