To solve this problem, we need to determine the locations of the internal nodes of the eigenfunctions \(\Psi_n(x)\) for a particle in a one-dimensional box. The potential for a particle confined in a one-dimensional box is given by:
\(V(x) = 0\) for \(0 \leq x \leq L\), and \(V(x) = \infty\) elsewhere.
The wave functions \(\Psi_n(x)\) of a particle in such a box are given by:
\(\Psi_n(x) = \sqrt{\frac{2}{L}} \sin\left(\frac{n\pi x}{L}\right)\) for \(n = 1, 2, 3, \ldots\)
Nodes are the points where the wave function is zero, other than the boundary points. For \(n \geq 2\), the wave function has \((n - 1)\) nodes between \(0\) and \(L\). These nodes occur at points where:
\(\sin\left(\frac{n\pi x}{L}\right) = 0\)
The sine function is zero at integer multiples of \(\pi\), so:
\(\frac{n\pi x}{L} = m\pi\) where \(m\) is an integer such that \(0 < m < n\).
Solving for \(x\), we get:
\(x = \frac{mL}{n}\)
This confirms that the locations of the internal nodes are given by \(x = \frac{m}{n} L\).
Now, let's examine the given options:
Therefore, the correct answer is \(x = \frac{m}{n} L\).
The figures below show:
Which of the following points in Figure 2 most accurately represents the nodal surface shown in Figure 1?
But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) Na/liq.NH₃ to give the products X and Y respectively.
Identify the incorrect statements.
A. X and Y are stereoisomers.
B. Dipole moment of X is zero.
C. Boiling point of X is higher than Y.
D. X and Y react with O₃/Zn + H₂O to give different products.
Choose the correct answer from the options given below :
One mole of a monoatomic ideal gas starting from state A, goes through B and C to state D, as shown in the figure. Total change in entropy (in J K\(^{-1}\)) during this process is ............... 
The number of chiral carbon centers in the following molecule is ............... 
A tube fitted with a semipermeable membrane is dipped into 0.001 M NaCl solution at 300 K as shown in the figure. Assume density of the solvent and solution are the same. At equilibrium, the height of the liquid column \( h \) (in cm) is ......... 