• \(NH_3\): The nitrogen atom is surrounded by three bonded atoms and one lone pair, resulting in an sp3 hybridization due to the tetrahedral arrangement.
• \(SO_2\): Sulfur in \(SO_2\) is sp2 hybridized because it forms two sigma bonds and has one lone pair, giving a bent structure.
• \(SiO_2\): Each silicon atom forms four sigma bonds with oxygen atoms. However, due to its extended lattice structure, we consider the local bonding, indicating sp3 hybridization for the central Si atom.
• \(BeCl_2\): The beryllium atom is sp hybridized as it forms two sigma bonds with chlorine atoms, leading to a linear geometry.
• \(CO_2\): Carbon in \(CO_2\) is sp hybridized since it forms two sigma bonds with oxygen atoms, resulting in a linear structure.
• \(H_2O\): The oxygen atom has two sigma bonds and two lone pairs, leading to sp3 hybridization, resulting in a bent structure.
• \(CH_4\): Carbon in \(CH_4\) is sp3 hybridized as it forms four sigma bonds, resulting in a tetrahedral geometry.
• \(BF_3\): Boron in \(BF_3\) is sp2 hybridized, as it forms three sigma bonds with fluorine atoms, resulting in a planar triangular structure.
Identify the correct orders against the property mentioned:
A. H$_2$O $>$ NH$_3$ $>$ CHCl$_3$ - dipole moment
B. XeF$_4$ $>$ XeO$_3$ $>$ XeF$_2$ - number of lone pairs on central atom
C. O–H $>$ C–H $>$ N–O - bond length
D. N$_2$>O$_2$>H$_2$ - bond enthalpy
Choose the correct answer from the options given below:
What is the empirical formula of a compound containing 40% sulfur and 60% oxygen by mass?
If the system of equations \[ x + 2y - 3z = 2, \quad 2x + \lambda y + 5z = 5, \quad 14x + 3y + \mu z = 33 \] has infinitely many solutions, then \( \lambda + \mu \) is equal to:}
The equilibrium constant for decomposition of $ H_2O $ (g) $ H_2O(g) \rightleftharpoons H_2(g) + \frac{1}{2} O_2(g) \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $ is $ 8.0 \times 10^{-3} $ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($ \alpha $) of water is _____ $\times 10^{-2}$ (nearest integer value). [Assume $ \alpha $ is negligible with respect to 1]