The natural frequencies of a pipe closed at one end are given by the formula: \[ f_n = \frac{n v}{4 L} \] Where:
- \( f_n \) is the frequency of the \( n \)-th harmonic,
- \( v = 340 \, \text{ms}^{-1} \) is the velocity of sound,
- \( L = 85 \, \text{cm} = 0.85 \, \text{m} \) is the length of the pipe. The frequencies for a closed-end pipe are given by the odd multiples of the fundamental frequency, so: \[ f_1 = \frac{v}{4 L}, \quad f_3 = 3 \cdot \frac{v}{4 L}, \quad f_5 = 5 \cdot \frac{v}{4 L}, \quad \dots \] We need to find the maximum \( n \) such that \( f_n<1250 \, \text{Hz} \). Calculating \( f_1 \): \[ f_1 = \frac{340}{4 \times 0.85} = 100 \, \text{Hz} \] Now we calculate the higher harmonics: \[ f_3 = 3 \times 100 = 300 \, \text{Hz}, \quad f_5 = 5 \times 100 = 500 \, \text{Hz}, \quad f_7 = 7 \times 100 = 700 \, \text{Hz}, \quad f_9 = 9 \times 100 = 900 \, \text{Hz}, \quad f_{11} = 11 \times 100 = 1100 \, \text{Hz}, \quad f_{13} = 13 \times 100 = 1300 \, \text{Hz} \] Since the frequency \( f_{13} = 1300 \, \text{Hz} \) exceeds 1250 Hz, we consider harmonics up to \( f_{11} \), which gives 6 possible oscillations (i.e., \( f_1, f_3, f_5, f_7, f_9, f_{11} \)).
Thus, the number of possible natural oscillations is \( 6 \).
Two loudspeakers (\(L_1\) and \(L_2\)) are placed with a separation of \(10 \, \text{m}\), as shown in the figure. Both speakers are fed with an audio input signal of the same frequency with constant volume. A voice recorder, initially at point \(A\), at equidistance to both loudspeakers, is moved by \(25 \, \text{m}\) along the line \(AB\) while monitoring the audio signal. The measured signal was found to undergo \(10\) cycles of minima and maxima during the movement. The frequency of the input signal is _____________ Hz.
(Speed of sound in air is \(324 \, \text{m/s}\) and \( \sqrt{5} = 2.23 \)) 
200 ml of an aqueous solution contains 3.6 g of Glucose and 1.2 g of Urea maintained at a temperature equal to 27$^{\circ}$C. What is the Osmotic pressure of the solution in atmosphere units?
Given Data R = 0.082 L atm K$^{-1}$ mol$^{-1}$
Molecular Formula: Glucose = C$_6$H$_{12}$O$_6$, Urea = NH$_2$CONH$_2$