The normality of H2SO4 in the solution obtained on mixing 100 mL of 0.1 M H2SO4 with 50 mL of 0.1 M NaOH is ________ × 10–1 N. (Nearest Integer)
The normality of H2SO4 in the solution obtained on mixing 100 mL of 0.1 M H2SO4 with 50 mL of 0.1 M NaOH is ________ × 10–1 N. (Nearest Integer)
Correct Answer: 1.01
Solution and Explanation
The correct answer is: 01.00
H2SO4+2NaOH→Na2SO4+H2O
Initial millimoles 10 5 - -
Final millimoles 7.5 - 2.5 -
Molarity of H2SO4 = 7.5/150 \(\frac{7.5}{150}\)=\(\frac{ 1}{20}\)M
Normality of H2SO4 = \(\frac{1}{20}\)×2 = 0.1N = 1×10-11/2N
Top Questions on Solutions
According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this concept is valid in ecological systems (isotopic mixtures of an element, hydrocarbons mixtures, etc.). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This law is further supported by the fact that Raoult’s law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.
Answer the following questions:
(a) Give one example of miscible liquid pair which shows negative deviation from Raoult’s law. What is the reason for such deviation?
(b) (i) State Raoult’s law for a solution containing volatile components.
OR
(ii) Raoult’s law is a special case of Henry’s law. Comment.
(c) Write two characteristics of an ideal solution.- A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
- Define Azeotrope. What type of Azeotrope is formed by negative deviation from Raoult's law? Give an example.
- Give reasons:
(a) Cooking is faster in a pressure cooker than in an open pan.
(b) On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation from Raoult's law is shown by the resulting solution? What change in temperature would you observe after mixing liquids X and Y? - An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because __________
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Concepts Used:
Concentration of Solutions
It is the amount of solute present in one liter of solution.
Concentration in Parts Per Million - The parts of a component per million parts (106) of the solution.
Mass Percentage - When the concentration is expressed as the percent of one component in the solution by mass it is called mass percentage (w/w).
Volume Percentage - Sometimes we express the concentration as a percent of one component in the solution by volume, it is then called as volume percentage
Mass by Volume Percentage - It is defined as the mass of a solute dissolved per 100mL of the solution.
Molarity - One of the most commonly used methods for expressing the concentrations is molarity. It is the number of moles of solute dissolved in one litre of a solution.
Molality - Molality represents the concentration regarding moles of solute and the mass of solvent.
Normality - It is the number of gram equivalents of solute present in one liter of the solution and it is denoted by N.
Formality - It is the number of gram formula present in one litre of solution.