The kinetic energies of an electron (\(e\)) and a proton (\(p\)) are \(E\) and \(3E\), respectively. Given that the mass of a proton is 1836 times that of an electron, the ratio of their de Broglie wavelengths (\(\lambda_e / \lambda_p\)) is ___________ (rounded off to two decimal places).
The de Broglie wavelength (\(\lambda\)) of a particle is given by the equation: \[ \lambda = \frac{h}{p} \] where \(h\) is Planck's constant and \(p\) is the momentum of the particle. The kinetic energy (\(K\)) of a particle is related to its momentum by: \[ K = \frac{p^2}{2m} \implies p = \sqrt{2mK} \] where \(m\) is the mass of the particle. For the electron (\(e\)), the kinetic energy is \(K_e = E\) and its mass is \(m_e\). The de Broglie wavelength of the electron is: \[ \lambda_e = \frac{h}{p_e} = \frac{h}{\sqrt{2m_e K_e}} = \frac{h}{\sqrt{2m_e E}} \] For the proton (\(p\)), the kinetic energy is \(K_p = 3E\) and its mass is \(m_p = 1836 m_e\). The de Broglie wavelength of the proton is: \[ \lambda_p = \frac{h}{p_p} = \frac{h}{\sqrt{2m_p K_p}} = \frac{h}{\sqrt{2(1836 m_e) (3E)}} = \frac{h}{\sqrt{11016 m_e E}} \] Now, we need to find the ratio of their de Broglie wavelengths (\(\lambda_e / \lambda_p\)): \[ \frac{\lambda_e}{\lambda_p} = \frac{\frac{h}{\sqrt{2m_e E}}}{\frac{h}{\sqrt{11016 m_e E}}} = \frac{\sqrt{11016 m_e E}}{\sqrt{2m_e E}} = \sqrt{\frac{11016 m_e E}{2m_e E}} \] \[ \frac{\lambda_e}{\lambda_p} = \sqrt{\frac{11016}{2}} = \sqrt{5508} \] \[ \sqrt{5508} \approx 74.2159 \] Rounding off to two decimal places, the ratio \(\lambda_e / \lambda_p\) is 74.22. This falls within the given range of 74.10 to 74.30.
The Lineweaver-Burk plot for an enzyme obeying the Michaelis-Menten mechanism is given below.
The slope of the line is \(0.36 \times 10^2\) s, and the y-intercept is \(1.20\) mol\(^{-1}\) L s. The value of the Michaelis constant (\(K_M\)) is ________ \( \times 10^{-3} \) mol L\(^{-1}\) (in integer). [Note: \(v\) is the initial rate, and \([S]_0\) is the substrate concentration]
Consider a Carnot engine with a hot source kept at 500 K. From the hot source, 100 J of energy (heat) is withdrawn at 500 K. The cold sink is kept at 300 K. The efficiency of the Carnot engine is ___________ (rounded off to one decimal place).
For the cell reaction, \[ Hg_2Cl_2 (s) + H_2 (1 \, {atm}) \rightarrow 2Hg (l) + 2H^+ (a=1) + 2Cl^- (a=1) \] The standard cell potential is \( \mathcal{E}^0 = 0.2676 \) V, and \( \left(\frac{\partial \mathcal{E}^0}{\partial T}\right)_P = -3.19 \times 10^{-4} \) V K\(^{-1}\). The standard enthalpy change of the reaction (\( \Delta_r H^0 \)) at 298 K is \( -x \) kJ mol\(^{-1}\). The value of \( x \) is ___________ (rounded off to two decimal places). [Given: Faraday constant \( F = 96500 \) C mol\(^{-1}\)]
The mean energy of a molecule having two available energy states at \( \epsilon = 0 \) J and \( \epsilon = 4.14 \times 10^{-21} \) J at 300 K is ___________ \( \times 10^{-21} \) J (rounded off to two decimal places). [Given: Boltzmann constant \( k_B = 1.38 \times 10^{-23} \) J K\(^{-1}\)]
Wavefunctions and energies for a particle confined in a cubic box are \( \psi_{n_x,n_y,n_z} \) and \( E_{n_x,n_y,n_z} \), respectively. The functions \( \phi_1, \phi_2, \phi_3 \), and \( \phi_4 \) are written as linear combinations of \( \psi_{n_x,n_y,n_z} \). Among these functions, the eigenfunction(s) of the Hamiltonian operator for this particle is/are \[ \phi_1 = \frac{1}{\sqrt{2}} \psi_{1,4,1} - \frac{1}{\sqrt{2}} \psi_{2,2,3} \] \[ \phi_2 = \frac{1}{\sqrt{2}} \psi_{1,5,1} + \frac{1}{\sqrt{2}} \psi_{3,3,3} \] \[ \phi_3 = \frac{1}{\sqrt{2}} \psi_{1,3,8} + \frac{1}{\sqrt{2}} \psi_{3,8,1} \] \[ \phi_4 = \frac{1}{2} \psi_{3,3,1} + \frac{\sqrt{3}}{2} \psi_{2,4,1} \]
The correct option(s) of reagents and reaction sequences suitable for carrying out the following transformation is/are
The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).
[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
The correct option with regard to the following statements is
(a) Time-independent Schrödinger equation can be exactly solved for Be\(^{2+}\).
(b) For a particle confined in a one-dimensional box of length \( l \) with infinite potential barriers, the trial variation function \( \phi = \left[ \left( \frac{3}{l^3} \right)^{1/2} x \right] \) is not an acceptable trial wavefunction for \( 0 \le x \le l \).
(c) Wavefunctions for system of Fermions must be anti-symmetric with respect to exchange of any two Fermions in the system.
(d) Born-Oppenheimer approximation can be used to separate the vibrational and rotational motion of a molecule.
Compound K displayed a strong band at 1680 cm−1 in its IR spectrum. Its 1H-NMR spectral data are as follows:
δ (ppm):
7.30 (d, J = 7.2 Hz, 2H)
6.80 (d, J = 7.2 Hz, 2H)
3.80 (septet, J = 7.0 Hz, 1H)
2.20 (s, 3H)
1.90 (d, J = 7.0 Hz, 6H)
The correct structure of compound K is: