Question:

The decreasing order of first ionization enthalpy of the following elements is:

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Elements with half-filled or fully filled orbitals have **higher ionization enthalpy** due to extra stability.
Updated On: Mar 10, 2025
  • \( N>O>C>Be \)
  • \( O>N>C>Be \)
  • \( Be>C>O>N \)
  • \( N>O>Be>C \)
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The Correct Option is A

Solution and Explanation

Ionization enthalpy generally increases across a period due to increasing effective nuclear charge. 
However, nitrogen has a half-filled p-orbital configuration (2p\(^3\)), which provides extra stability, making its ionization enthalpy higher than oxygen. 
Thus, the correct order is: \[ N > O > C > Be \]

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