The condition for the de-Broglie wavelength of an electron in an orbit is given by:
\[ 2 \pi r_n = n \lambda_d \]
where \( r_n \) is the radius of the \( n \)-th orbit, \( n \) is the principal quantum number, and \( \lambda_d \) is the de-Broglie wavelength.
The radius of the \( n \)-th orbit in the Bohr model is given by:
\[ r_n = 2 \pi a_0 \frac{n^2}{Z} \]
Substituting this into the equation:
\[ 2 \pi a_0 \frac{n^2}{Z} = n \lambda_d \]
For an electron in the 4th orbit and for a hydrogen atom (\( Z = 1 \)):
\[ 2 \pi a_0 \frac{4^2}{1} = 4 \lambda_d \]
Simplifying:
\[ \lambda_d = 8 \pi a_0 \]
Hence, the de-Broglie's wavelength of the electron in the 4th orbit is \( 8 \pi a_0 \).
The de Broglie wavelengths of a proton and an \(\alpha\) particle are \(λ_p\) and \(λ_\alpha\) respectively. The ratio of the velocities of proton and \(\alpha\) particle will be :