The correct order of the ease of dehydration of the following alcohols by the action of conc. H2SO4 is:
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The stability of carbocations increases with the number of alkyl groups attached to the central carbon. Tertiary carbocations are the most stable and lead to the fastest dehydration.
The ease of dehydration is based on the stability of the carbocation formed during the reaction. Tertiary alcohols (like (CH3)3C – OH
undergo dehydration the most easily due to the formation of a stable tertiary carbocation.