In acidic medium, only iodide ions (I\(^-\)) can be oxidized by oxygen to form iodine (\( \text{I}_2 \)). The reaction is as follows: \[ 4 \text{I}^- + 4 \text{H}^+ + \text{O}_2 \rightarrow 2 \text{I}_2 (s) + 2 \text{H}_2\text{O} (l). \] Chloride (Cl\(^-\)) and bromide (Br\(^-\)) ions are not oxidized by oxygen in acidic medium because their reduction potentials are not favorable for such oxidation under standard conditions.
(b.)Calculate the potential for half-cell containing 0.01 M K\(_2\)Cr\(_2\)O\(_7\)(aq), 0.01 M Cr\(^{3+}\)(aq), and 1.0 x 10\(^{-4}\) M H\(^+\)(aq).
A molecule with the formula $ \text{A} \text{X}_2 \text{Y}_2 $ has all it's elements from p-block. Element A is rarest, monotomic, non-radioactive from its group and has the lowest ionization energy value among X and Y. Elements X and Y have first and second highest electronegativity values respectively among all the known elements. The shape of the molecule is:
A transition metal (M) among Mn, Cr, Co, and Fe has the highest standard electrode potential $ M^{n}/M^{n+1} $. It forms a metal complex of the type $[M \text{CN}]^{n+}$. The number of electrons present in the $ e $-orbital of the complex is ... ...
Consider the following electrochemical cell at standard condition. $$ \text{Au(s) | QH}_2\text{ | QH}_X(0.01 M) \, \text{| Ag(1M) | Ag(s) } \, E_{\text{cell}} = +0.4V $$ The couple QH/Q represents quinhydrone electrode, the half cell reaction is given below: $$ \text{QH}_2 \rightarrow \text{Q} + 2e^- + 2H^+ \, E^\circ_{\text{QH}/\text{Q}} = +0.7V $$
0.1 mol of the following given antiviral compound (P) will weigh .........x $ 10^{-1} $ g.
Consider the following equilibrium, $$ \text{CO(g)} + \text{H}_2\text{(g)} \rightleftharpoons \text{CH}_3\text{OH(g)} $$ 0.1 mol of CO along with a catalyst is present in a 2 dm$^3$ flask maintained at 500 K. Hydrogen is introduced into the flask until the pressure is 5 bar and 0.04 mol of CH$_3$OH is formed. The $ K_p $ is ...... x $ 10^7 $ (nearest integer).
Given: $ R = 0.08 \, \text{dm}^3 \, \text{bar} \, \text{K}^{-1} \, \text{mol}^{-1} $
Assume only methanol is formed as the product and the system follows ideal gas behavior.