Step 1: A secondary hydrogen is one that is attached to a carbon atom that is itself attached to two other carbon atoms.
Step 2: In 2,2,3-Tetramethylpentane, the carbon atoms at positions 2 and 3 have two other carbon atoms attached, and the hydrogens attached to these carbons are secondary hydrogens.
Step 3: Other options do not exhibit the same secondary hydrogen placement.
Thus, the correct answer is 2,2,3-Tetramethylpentane.

Let \( a \in \mathbb{R} \) and \( A \) be a matrix of order \( 3 \times 3 \) such that \( \det(A) = -4 \) and \[ A + I = \begin{bmatrix} 1 & a & 1 \\ 2 & 1 & 0 \\ a & 1 & 2 \end{bmatrix} \] where \( I \) is the identity matrix of order \( 3 \times 3 \).
If \( \det\left( (a + 1) \cdot \text{adj}\left( (a - 1) A \right) \right) \) is \( 2^m 3^n \), \( m, n \in \{ 0, 1, 2, \dots, 20 \} \), then \( m + n \) is equal to: