Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: H2Te is more acidic than H2S.
Reason R: Bond dissociation enthalpy of H2Te is lower than H2S.
In light of the above statements, choose the most appropriate from the options given below:
Understanding Assertion A: The acidity of hydrogen compounds such as H2S and H2Te can be compared based on the stability of the conjugate base formed after deprotonation. H2Te has a larger atomic size and weaker H–Te bonds compared to H–S, which leads to easier ionization of H2Te and thus higher acidity.
Understanding Reason R: The bond dissociation enthalpy is a measure of the strength of the bond between hydrogen and the other element (S or Te). Since H–Te bonds are weaker than H–S bonds, H2Te dissociates more easily, supporting the assertion that H2Te is more acidic than H2S.
Therefore, the correct interpretation of both statements shows that both Assertion A and Reason R are true, and R indeed provides the correct explanation for A.
Arrange the following compounds in increasing order of their reactivity towards \( S_N2 \) displacement: 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane.
In the following pair of halogen compounds, which compound undergoes \( S_N1 \) reaction faster and why?
Assertion (A): Aromatic primary amines cannot be prepared by Gabriel Phthalimide synthesis.
Reason (R): Aryl halides do not undergo nucleophilic substitution reaction with the anion formed by phthalimide.
If the system of equations \[ x + 2y - 3z = 2, \quad 2x + \lambda y + 5z = 5, \quad 14x + 3y + \mu z = 33 \] has infinitely many solutions, then \( \lambda + \mu \) is equal to:}
The equilibrium constant for decomposition of $ H_2O $ (g) $ H_2O(g) \rightleftharpoons H_2(g) + \frac{1}{2} O_2(g) \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $ is $ 8.0 \times 10^{-3} $ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($ \alpha $) of water is _____ $\times 10^{-2}$ (nearest integer value). [Assume $ \alpha $ is negligible with respect to 1]
The chemical coordination and integration of all physiological functions in the animal body are jointly synchronized by the neural and endocrine systems. The control and coordination of body functions are executed by the endocrine glands. They are ductless glands that secrete severel hormones to control and coordinate body functions.
The human body has several endocrine glands located in different parts. They cover the pituitary gland, thymus, thyroid gland, pineal gland, parathyroid, pancreas (dual gland), adrenal gland, and gonads (testes and ovaries). The liver, kidney, heart, and gastrointestinal tract also produce hormones in small traces to harmonize the functioning of these organs.
The Hypothalamus comprises groups of secretory cells called nuclei which secrets various hormones. These hormones released by the hypothalamus are important in regulating the synthesis and secretion of pituitary hormones.