For a first-order reaction:
\[ t_{1/2} = 120 \, \text{min} \]For 90% completion:
\[ t = \frac{2.303}{k} \log \left( \frac{a}{a - x} \right) \] \[ t = \frac{2.303 \times 120}{0.693} \log \left( \frac{100}{10} \right) \] \[ t = 399 \, \text{min}. \]The following data were obtained during the first order thermal decomposition of \( \text{N}_2\text{O}_5(g) \) at constant volume: