Question

P-T diagram of an ideal gas having three different densities \( \rho_1, \rho_2, \rho_3 \) (in three different cases) is shown in the figure. Which of the following is correct:

• A. \( \rho_2 < \rho_3 \)
• B. \( \rho_1 > \rho_2 \)
• C. \( \rho_1 < \rho_2 \)
• D. \( \rho_1 = \rho_2 = \rho_3 \)

Answer 1

The Correct Option is B

Ideal Gas Equation and Density Relationship:

For an ideal gas, the equation is given by:

\( PV = nRT \)

or,

\( P = \frac{nRT}{V} \)

where \( P \) is the pressure, \( T \) is the temperature, \( R \) is the gas constant, \( n \) is the number of moles, and \( V \) is the volume.

We can express \( P \) in terms of density \( \rho \) by substituting \( \rho = \frac{m}{V} \), where \( m \) is the mass of the gas:

\( P = \frac{\rho RT}{M} \)

where \( M \) is the molar mass of the gas. Rearranging, we get:

\( \rho = \frac{PM}{RT} \)

Analyze the PT Graph for Different Densities:

Since \( \rho = \frac{PM}{RT} \), for a given temperature \( T \), the density \( \rho \) of the gas is directly proportional to the pressure \( P \):

\( \rho \propto P \)

Therefore, at the same temperature, a higher pressure indicates a higher density.

Interpretation of the PT Diagram:

In the given PT diagram, we observe that:

\( P_1 > P_2 > P_3 \) for the same temperature \( T \)

Therefore, based on the proportional relationship \( \rho \propto P \) at constant temperature, we have:

\( \rho_1 > \rho_2 > \rho_3 \)

Conclusion:

The correct statement is: \( \rho_1 > \rho_2 \) which corresponds to Option (2).