In the monochlorination of 2-methylbutane, chlorine can replace a hydrogen atom at different positions, leading to the formation of structural and stereoisomeric products. The possible isomeric products are:
CH3−CH(Cl)−CH2−CH(CH3)−CH3(±)
CH3−CH(CH3)−CH2−CH(Cl)−CH3
CH3−C(Cl)(CH3)−CH2−CH3(±)
Therefore, there are 6 isomeric products.