Question:

Number of metal ions characterized by flame test among the following is _______.
$\text{Sr}^{2+}, \text{Ba}^{2+}, \text{Ca}^{2+}, \text{Cu}^{2+}, \text{Zn}^{2+}, \text{Co}^{2+}, \text{Fe}^{2+}$

Updated On: Nov 4, 2025
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Correct Answer: 4

Approach Solution - 1

To determine the number of metal ions that can be characterized by a flame test, we need to know which of the given ions produce characteristic colors upon heating in a flame.

Analysis of Each Metal Ion:

  • Sr2+: Produces a bright red flame.
  • Ba2+: Produces a green flame.
  • Ca2+: Produces an orange-red flame.
  • Cu2+: Produces a blue-green flame.
  • Zn2+: Typically does not produce a distinct color in a flame test.
  • Co2+: Produces a blue flame.
  • Fe2+: Produces a yellow-green flame, but is less distinctive and often masked by other colors.

Summary of Metal Ions with Characteristic Flames: Characteristic colors are seen with Sr2+, Ba2+, Ca2+, Cu2+.

Counting those that yield distinct flame colors: Sr2+, Ba2+, Ca2+, Cu2+

Thus, the total number of metal ions characterized by flame tests from the list is: 4

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Approach Solution -2

Determine how many of the given metal ions can be characterized (identified) by a flame test.

Concept Used:

The flame test is used to identify certain metal ions based on the characteristic color they impart to a flame. This occurs when heat excites the metal ions' electrons to higher energy levels; as they fall back, they emit light of specific wavelengths. Not all metal ions produce a characteristic flame color that is useful for identification.

Step-by-Step Solution:

Step 1: List the characteristic flame colors for common metal ions:

  • Strontium (Sr2+): Crimson red
  • Barium (Ba2+): Apple green
  • Calcium (Ca2+): Brick red
  • Copper (Cu2+): Blue-green (often with flashes of other colors)

Step 2: Analyze Sr2+. It gives a characteristic crimson red flame. Yes, characterized by flame test.

Step 3: Analyze Ba2+. It gives a characteristic apple green flame. Yes, characterized by flame test.

Step 4: Analyze Ca2+. It gives a characteristic brick red flame. Yes, characterized by flame test.

Step 5: Analyze Cu2+. It gives a characteristic blue-green flame. Yes, characterized by flame test.

Step 6: Analyze Zn2+. It does not give a characteristic flame color that is useful for identification. No.

Step 7: Analyze Co2+. It does not give a characteristic flame color that is useful for identification. No.

Step 8: Analyze Fe2+. It does not give a characteristic flame color that is useful for identification. No.

Thus, the metal ions characterized by flame test are: Sr2+, Ba2+, Ca2+, and Cu2+.

The number of metal ions characterized by flame test among the given list is 4.

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Concepts Used:

D and F Block Elements

The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements. 

They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.

Read More: The d and f block elements