When \( n \) identical cells are connected in series, the total effective e.m.f. is:
\[
E_{\text{total}} = nE
\]
If two cells are connected in reverse polarity, their individual e.m.f. will subtract from the total e.m.f.:
\[
E'_{\text{total}} = (n-2)E
\]
However, the potential difference across a single reversed cell ‘X’ is equal to the sum of the e.m.f. of the reversed cells, which is:
\[
V_X = 2E
\]
Thus, the potential difference across cell ‘X’ is \( 2E \).