Question:

Match List I with List II 
Molecules/Ions
Choose the correct answer from the options given below:

Updated On: Jan 9, 2025
  • A - IV, B - I, C - II, D - III
  • A - II, B - I, C - IV, D - III
  • A - II, B - III, C - IV, D - I
  • A - IV, B - III, C - II, D - I
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The Correct Option is D

Solution and Explanation

Step 1: Determine the Lone Pairs for Each Molecule/Ion
The number of lone pairs on the central atom can be determined using the following steps:
Count the total valence electrons of the central atom.
Subtract the electrons used for bonding with surrounding atoms.
Divide the remaining electrons by 2 to get the number of lone pairs.
Step 2: Analyze Each Molecule/Ion
\(\text{IF}_7\): Iodine has 7 valence electrons. All are used for bonding with 7 fluorine atoms. Therefore, 0 lone pairs (IV).
\(\text{ICl}_4^-\): Iodine has 7 valence electrons and gains 1 due to the negative charge. Four are used for bonding with chlorine atoms, leaving 4 electrons (2 lone pairs). Therefore, 2 lone pairs (III).
\(\text{XeF}_6\): Xenon has 8 valence electrons. Six are used for bonding with fluorine atoms, leaving 2 electrons (1 lone pair). Therefore, 1 lone pair (II).
\(\text{XeF}_2\): Xenon has 8 valence electrons. Two are used for bonding with fluorine atoms, leaving 6 electrons (3 lone pairs). Therefore, 3 lone pairs (I)}

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Concepts Used:

P-Block Elements

  • P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
  • P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.

P block elements consist of: