For \(f(x) = 2^x - x^2 = 0\), we determine the values of \(x\) where this equation holds. This equation intersects the x-axis at three points, so \(m = 3\).
The derivative \(f'(x) = 2^x \ln 2 - 2x\). Setting \(f'(x) = 0\), we solve \(2^x \ln 2 = 2x\) to find the points where this equation intersects the x-axis. This yields two intersection points, so \(n = 2\).
\[ m + n = 3 + 2 = 5 \]
So, the correct answer is: 5