Given \( a = 2b + 1 \), we can solve for \( b \) as follows:
\[
b = \frac{a - 1}{2}
\]
The set \( R \) is given by \( \{(3, 1), (5, 2), \dots, (99, 49)\} \). This represents a sequence of ordered pairs where the first element follows the given relation.
Let \( (2m + 1, m) \), \( (2n - 1, n) \), etc., be such ordered pairs. From the condition, we have:
\[
m = 2a - 1 \quad \Rightarrow \quad m \, \text{is odd number}
\]
The first element of ordered pair \( (a, b) \) is:
\[
a = 2(2a - 1) + 1 = 4a - 1
\]
Hence, \( a = \{3, 7, 11, \dots, 99\} \).
For maximum number of ordered pairs in such a sequence, we need to solve for \( \lambda \). This gives us the largest sequence length.
\[
\lambda = 2a - 1
\]
The number of terms in this sequence satisfies:
\[
\lambda \in \{1, 2, 3, \dots, 25\}
\]
Thus, for maximum ordered pairs, we evaluate cases for various values of \( \lambda \). The final maximum value of \( r \) for \( \lambda = 16 \) is 5.