IUPAC name of the compound \(K_{3}[Co(C_{2}O_{4})_{3}]\) is
- Potassium trioxalatocobaltate (III)
- Potassium trioxalatocobaltate (III)
- Potassium cobalt tris oxalate (II)
- Potassium oxalato cobaltate (III)
The Correct Option is B
Approach Solution - 1
Therefore, the IUPAC name of \(K_{3}[Co(C_{2}O_{4})_{3}]\) is Potassium trioxalatocobaltate (III)
Approach Solution -2
IUPAC Nomenclature of Coordination Compound
The IUPAC name of \( \text{K}_3[\text{Co}(\text{C}_2\text{O}_4)_3] \) is Potassium trioxalatocobaltate(III).
The oxalate anion ( \( \text{C}_2\text{O}_4^{2-} \) ) is a bidentate ligand, and the prefix "tri" indicates there are three oxalate ligands.
The complex anion is \( [\text{Co}(\text{C}_2\text{O}_4)_3]^{3-} \), and since the potassium ion has a +1 charge, there must be three potassium ions to balance the charge.
The oxidation state of cobalt is +3, indicated by the Roman numeral (III).
Approach Solution -3
Top Questions on coordination compounds
Given below are two statements regarding conformations of n-butane. Choose the correct option.
- JEE Main - 2026
- Chemistry
- coordination compounds
- The correct statement among the following is:
- JEE Main - 2026
- Chemistry
- coordination compounds
Consider a weak base \(B\) of \(pK_b = 5.699\). \(x\) mL of \(0.02\) M HCl and \(y\) mL of \(0.02\) M weak base \(B\) are mixed to make \(100\) mL of a buffer of pH \(=9\) at \(25^\circ\text{C}\). The values of \(x\) and \(y\) respectively are
- JEE Main - 2026
- Chemistry
- coordination compounds
- \(20.0\,\text{dm}^3\) of an ideal gas \(X\) at \(600\) K and \(0.5\) MPa undergoes isothermal reversible expansion until the pressure of the gas becomes \(0.2\) MPa. Which of the following option is correct? (Given: \(\log 2 = 0.3010\), \(\log 5 = 0.6989\))
- JEE Main - 2026
- Chemistry
- coordination compounds
- From the following : (A) $[\text{Co}(\text{NH}_3)_6]^{3+}$ : Inner orbital complex, $d^2sp^3$ hybridization (B) $[\text{MnCl}_4]^{2-}$ : Outer orbital complex, $sp^3d^2$ hybridization (C) $[\text{CoF}_6]^{3-}$ : Outer orbital complex, $d^2sp^3$ hybridization (D) $[\text{FeF}_6]^{3-}$ : Outer orbital complex, $sp^3d^2$ hybridization (E) $[\text{Ni}(\text{CN})_4]^{2-}$ : Inner orbital complex, $sp^3$ hybridization Choose the correct answer from the given options.
- JEE Main - 2026
- Chemistry
- coordination compounds
Questions Asked in JEE Main exam
- For two identical cells each having emf \(E\) and internal resistance \(r\), the current through an external resistor of \(6\,\Omega\) is the same when the cells are connected in series as well as in parallel. The value of the internal resistance \(r\) is ________ \(\Omega\).
- JEE Main - 2026
- Current electricity
- For three unit vectors \( \vec a, \vec b, \vec c \) satisfying \[ |\vec a-\vec b|^2 + |\vec b-\vec c|^2 + |\vec c-\vec a|^2 = 9 \] and \[ |2\vec a + k\vec b + k\vec c| = 3, \] the positive value of \( k \) is:
- JEE Main - 2026
- Vector Algebra
In the given figure, the blocks $A$, $B$ and $C$ weigh $4\,\text{kg}$, $6\,\text{kg}$ and $8\,\text{kg}$ respectively. The coefficient of sliding friction between any two surfaces is $0.5$. The force $\vec{F}$ required to slide the block $C$ with constant speed is ___ N.
(Given: $g = 10\,\text{m s}^{-2}$)
- JEE Main - 2026
- Rotational Mechanics
- The system of linear equations
$x + y + z = 6$
$2x + 5y + az = 36$
$x + 2y + 3z = b$
has- JEE Main - 2026
- Matrices and Determinants
Method used for separation of mixture of products (B and C) obtained in the following reaction is:
- JEE Main - 2026
- p -Block Elements
Concepts Used:
Nomenclature of Coordination Compounds
Nomenclature of Coordination Compounds is important in Coordination Chemistry because of the need to have an unambiguous method of describing formulas and writing systematic names, particularly when dealing with isomers.
We can apply the following formulas:
- On the very first the central atom is listed.
- Ligands are then listed in alphabetical order and their placement in the list does not depend on their charge.
- Polydentate ligands are also listed alphabetically. In such a case of an abbreviated ligand, the first letter of the abbreviation is used to determine the position of the ligand in alphabetical order.
- The formula for the entire coordination entity is enclosed in square brackets whether charged or not. The formulas are enclosed in parentheses when ligands are polyatomic. Ligand abbreviations are also enclosed in parentheses.
- Within a coordination sphere, there should be no space between the ligands and the metal.
- When the formula of a charged coordination entity is to be written without that of the counter-ions, the charge is indicated outside the square brackets as a right superscript with the number before the sign. For example, [Co(CN)6]3-, [Cr(H2O)6]3+, etc.
- The charge of the anion(s) balances the charge of the cation(s).