Question:
In which pairs, the first ion is more stable than the second?
In which pairs, the first ion is more stable than the second?
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Resonance and inductive effects play a key role in the stability of ions, with electron-donating groups increasing stability and electron-withdrawing groups decreasing it.
Updated On: Apr 23, 2025
- (B) \& (D) only
- (A) \& (B) only
- (B) \& (C) only
- (A) \& (C) only
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The Correct Option is B
Solution and Explanation
In the pair (A), the ion with the methoxy group (\( \text{OMe} \)) is more stable than the one with the methyl group (\( \text{Me} \)) because the oxygen in the methoxy group can donate electron density via resonance, making it more stable.
In pair (B), the nitro group (\( \text{NO}_2 \)) is an electron-withdrawing group, making the ion less stable than the one with the oxygen-nitrogen double bond (\( \text{O,N} \)), which stabilizes the ion through resonance.
Thus, the correct answer is (2).
Thus, the correct answer is (2).
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