Question:

In the neutral or faintly alkaline medium, KMnO4 oxidises iodide into iodate. The change in oxidation state of manganese in this reaction is from

Updated On: May 2, 2025
  • (+7 to +4)
  • (+6 to +4)
  • (+7 to +3)
  • (+6 to +5)
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The Correct Option is A

Solution and Explanation

In the given reaction, KMnO4 acts as an oxidizing agent, and iodide (I-) is oxidized to iodate (IO3-). In an alkaline or neutral medium, the balanced equation for the oxidation process is as follows: 

2 KMnO4 + H2O + I- → 2 MnO2 + 2 KOH + IO3-

To determine the change in the oxidation state of manganese (Mn), let's analyze its transformation in the reaction:

  • In KMnO4, Mn is in the +7 oxidation state.
  • In MnO2, Mn is in the +4 oxidation state.

Thus, the change in the oxidation state of manganese is from +7 in KMnO4 to +4 in MnO2.

The correct answer to the change in oxidation state of manganese is (+7 to +4).

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