In the given reactions identify the reagent A and reagent B
- \( A-\text{CrO}_3 \quad B-\text{CrO}_3\)
- \(A-\text{CrO}_3 \quad B-\text{CrO}_2\text{Cl}_2\)
- \(A-\text{CrO}_2\text{Cl}_2 \quad B-\text{CrO}_2\text{Cl}_2\)
- \(A-\text{CrO}_2\text{Cl}_2 \quad B-\text{CrO}_3\)
The Correct Option is B
Solution and Explanation
Step 1: The reaction starts with toluene, which is oxidized by reagent A (CrO3) in acetic anhydride (CH3CO)2O. This oxidation step is known as the Etard reaction, where toluene is converted into benzylidene diacetate as an intermediate.
Step 2: The intermediate benzylidene diacetate is then treated with reagent B (CrO2Cl2), followed by hydrolysis (H2O+) to yield benzaldehyde (C6H5CHO).
Thus, the correct reagents are A-CrO3 and B-CrO2Cl2, which is represented by option (2).
Top Questions on Organic Chemistry
- Which one of the following compounds can exist as cis-trans isomers?
- NEET (UG) - 2025
- Chemistry
- Organic Chemistry
- Given below are two statements:
Statement I: Benzendiazonium salt is prepared by the reaction of aniline with nitrous acid at 273-278 K. It decomposes easily in the dry state.
Statement II: Insertion of iodine into the benzene ring is difficult and hence iodobenzene is prepared through the reaction of benzendiazonium salt with KI.
In the light of the above statements, choose the most appropriate answer from the options given below:- NEET (UG) - 2025
- Chemistry
- Organic Chemistry
Identify the suitable reagent for the following conversion: $Ph-C(=O)-OCH_3$ $\longrightarrow$ $Ph-CHO$
- NEET (UG) - 2025
- Chemistry
- Organic Chemistry
Why is chlorobenzene resistant to nucleophilic substitution reactions?
- CBSE CLASS XII - 2025
- Chemistry
- Organic Chemistry
- The conversion of phenol to salicylic acid can be accomplished by
- CBSE CLASS XII - 2025
- Chemistry
- Organic Chemistry
Questions Asked in JEE Main exam
If the system of equations \[ x + 2y - 3z = 2, \quad 2x + \lambda y + 5z = 5, \quad 14x + 3y + \mu z = 33 \] has infinitely many solutions, then \( \lambda + \mu \) is equal to:}
- JEE Main - 2025
- Calculus
- An electric dipole of mass \( m \), charge \( q \), and length \( l \) is placed in a uniform electric field \( E = E_0 \hat{i} \). When the dipole is rotated slightly from its equilibrium position and released, the time period of its oscillations will be:
- JEE Main - 2025
- Electric Dipole
The equilibrium constant for decomposition of $ H_2O $ (g) $ H_2O(g) \rightleftharpoons H_2(g) + \frac{1}{2} O_2(g) \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $ is $ 8.0 \times 10^{-3} $ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($ \alpha $) of water is _____ $\times 10^{-2}$ (nearest integer value). [Assume $ \alpha $ is negligible with respect to 1]
- JEE Main - 2025
- Law Of Chemical Equilibrium And Equilibrium Constant
- The distance of the point \( P(1, 2, 3) \) from the plane \( 3x - 4y + 12z - 7 = 0 \) is:
- JEE Main - 2025
- Geometry and Vectors
- Two iron solid discs of negligible thickness have radii \( R_1 \) and \( R_2 \) and moment of inertia \( I_1 \) and \( I_2 \), respectively. For \( R_2 = 2R_1 \), the ratio of \( I_1 \) and \( I_2 \) would be \( \frac{1}{x} \), where \( x \) is:
- JEE Main - 2025
- System of Particles & Rotational Motion