Step 1: Understanding Closest Distance of Approach The closest distance of approach \( r_{\text{min}} \) of an \(\alpha\) particle in Rutherford scattering is given by: \[ r_{\text{min}} = \frac{1}{4\pi \epsilon_0} \frac{2 Z e^2}{K} \] where:
- \( Z \) is the atomic number of the nucleus,
- \( e \) is the charge of the electron,
- \( K \) is the initial kinetic energy of the \(\alpha\) particle.
Step 2: Effect of Doubling Speed Kinetic energy is related to speed as: \[ K = \frac{1}{2} m v^2 \] If the initial speed of the \(\alpha\) particle is doubled: \[ K' = \frac{1}{2} m (2v)^2 = 4K \] Since \( r_{\text{min}} \) is inversely proportional to \( K \): \[ r_{\text{min}}' = \frac{r_{\text{min}}}{4} \] Thus, the closest distance of approach becomes one-fourth of its original value. Thus, the correct answer is \( \mathbf{(4)} \) becomes one-fourth.
Observe the following data given in the table. (\(K_H\) = Henry's law constant)
| Gas | CO₂ | Ar | HCHO | CH₄ |
|---|---|---|---|---|
| \(K_H\) (k bar at 298 K) | 1.67 | 40.3 | \(1.83 \times 10^{-5}\) | 0.413 |
The correct order of their solubility in water is
For a first order decomposition of a certain reaction, rate constant is given by the equation
\(\log k(s⁻¹) = 7.14 - \frac{1 \times 10^4 K}{T}\). The activation energy of the reaction (in kJ mol⁻¹) is (\(R = 8.3 J K⁻¹ mol⁻¹\))
Note: The provided value for R is 8.3. We will use the more precise value R=8.314 J K⁻¹ mol⁻¹ for accuracy, as is standard.