Radius of the circle:
\[
R = 6\sqrt{2} \text{ cm}.
\]
Let $d_1$ and $d_2$ be the perpendicular distances from $C$ to chords $PQ$ and $SR$ respectively, with
\[
d_1 : d_2 = 3 : 2.
\]
Step 1: Length of chord $PQ$.
Drop a perpendicular from $C$ to $PQ$ at $M$. Then $CM = d_1$ and $M$ is the midpoint of $PQ$.
Given $\angle PQC = 45^\circ$. Since $CM \perp PQ$ and $C$ lies on the perpendicular from the center to the chord, $\triangle CMQ$ is right-angled at $M$, with $CQ$ as the hypotenuse.
In $\triangle CMQ$:
\[
CQ = R = 6\sqrt{2}, \quad \angle MQC = 45^\circ.
\]
Then
\[
CM = CQ \sin 45^\circ
= 6\sqrt2 \cdot \frac{1}{\sqrt2}
= 6.
\]
So,
\[
d_1 = CM = 6 \text{ cm}.
\]
Also,
\[
MQ = CQ \cos 45^\circ
= 6\sqrt2 \cdot \frac{1}{\sqrt2}
= 6.
\]
Since $M$ is the midpoint,
\[
PQ = 2\cdot MQ = 12 \text{ cm}.
\]
Step 2: Length of chord $SR$.
Let $CN = d_2$ be the perpendicular distance from $C$ to chord $SR$, with $N$ the midpoint of $SR$.
Given
\[
d_1 : d_2 = 3 : 2,\quad d_1 = 6,
\]
so
\[
\frac{6}{d_2} = \frac{3}{2}
\Rightarrow 3d_2 = 12
\Rightarrow d_2 = 4 \text{ cm}.
\]
Now in right-angled $\triangle CNR$ (with $CR = R$ and $CN = 4$):
\[
CR^2 = CN^2 + NR^2
\Rightarrow (6\sqrt2)^2 = 4^2 + NR^2
\Rightarrow 72 = 16 + NR^2
\Rightarrow NR^2 = 56
\Rightarrow NR = \sqrt{56} = 2\sqrt{14}.
\]
Thus,
\[
SR = 2\cdot NR = 4\sqrt{14} \text{ cm}.
\]
Step 3: Area of quadrilateral $PQRS$.
Since $PQ \parallel SR$ and they lie on opposite sides of the center, $PQRS$ is a trapezium. Its height is the distance between the two chords, equal to:
\[
h = d_1 + d_2 = 6 + 4 = 10 \text{ cm}.
\]
Parallel sides:
\[
a = PQ = 12,\quad b = SR = 4\sqrt{14}.
\]
Area formula for a trapezium:
\[
\text{Area} = \frac{1}{2}(a + b)h
= \frac{1}{2}(12 + 4\sqrt{14}) \cdot 10
= 5(12 + 4\sqrt{14})
= 60 + 20\sqrt{14}.
\]
Factor:
\[
\text{Area} = 20(3 + \sqrt{14}) \text{ sq. cm}.
\]
\[
\boxed{20(3 + \sqrt{14})}
\]