For a matrix to be singular, its determinant must be zero. The determinant of a 2x2 matrix is given by:
\[
{det}(A) = (x) \cdot (x - 5) - (-3) \cdot (2)
\]
Simplifying, we get:
\[
{det}(A) = x(x - 5) + 6
\]
\[
= x^2 - 5x + 6
\]
Now, set the determinant equal to zero to make the matrix singular:
\[
x^2 - 5x + 6 = 0
\]
Factor the quadratic equation:
\[
(x - 2)(x - 3) = 0
\]
This gives the solutions:
\[
x = 2 \quad {or} \quad x = 3
\]
The sum of the values of \(x\) is:
\[
2 + 3 = 5
\]
Thus, the sum of the values of \(x\) is \(5\), which corresponds to option (A).