For an ideal gas, the slopes of the adiabatic and isothermal curves are related to the specific heat capacities and the ratio of specific heats \( \gamma \).
The general relationship between the slopes of the adiabatic and isothermal curves is given by: \[ \frac{c_p}{c_v} = \gamma \] The slope of the adiabatic curve \( m_a \) and the slope of the isothermal curve \( m_i \) are related through the ratio of specific heats \( \gamma \).
From the ideal gas laws and thermodynamic relationships, we know that: \[ m_a = \gamma m_i \]
Thus, the correct relationship between the slopes is \( m_a = \gamma m_i \).
The standard heat of formation, in kcal/mol, of $Ba^{2+}$ is:
Given: Standard heat of formation of SO₄²⁻(aq) = -216 kcal/mol, standard heat of crystallization of BaSO₄(s) = -4.5 kcal/mol, standard heat of formation of BaSO₄(s) = -349 kcal/mol.