Using the simple interest formula:
\[
SI = \frac{P \times R \times T}{100}
\]
Since the amount doubles, \( A = P + SI = 2P \), so:
\[
P + P \times \frac{R \times T}{100} = 2P
\]
\[
P \times \frac{R \times T}{100} = P
\]
\[
R \times T = 100
\]
For \( T = 5 \) years:
\[
R = \frac{100}{5} = 20%
\]
Thus, the correct answer is 20% per annum.