If \(\vec{a}=\hat{i}+\hat{j}+\hat{k},\vec{b}=2\hat{i}-\hat{j}+3\hat{k}\) and \(\vec{c}=\hat{i}-2\hat{j}+\hat{k}\),find a unit vector parallel to the vector \(2\vec{a}-\vec{b}+3\vec{c}.\)
We have,
\(\vec{a}=\hat{i}+\hat{j}+\hat{k},\vec{b}=2\hat{i}-\hat{j}+3\hat{k}\),and \(\vec{c}=\hat{i}-2\hat{j}+\hat{k}\)
\(2\vec{a}-\vec{b}+3\vec{c}\)\(=2(\hat{i}+\hat{j}+\hat{k})-(2\hat{i}-\hat{j}+3\hat{k})+3\hat{(i}-2\hat{j}+\hat{k})\)
\(=2/hat{i}+2\hat{j}+2\hat{k}-2\hat{i}+\hat{j}-3\hat{k}+3\hat{i}-6\hat{j}+3\hat{k}\)
\(=3\hat{i}-3\hat{j}+2\hat{k}\)
\(|2\vec{a}-\vec{b}+3\vec{c}|=\sqrt{3^{2}+(-3)^{2}+2^{2}}=\sqrt{9+9+4}=\sqrt{22}\)
Hence,the unit vector along \(2\vec{a}-\vec{b}+3\vec{c}\) is
\(\frac{2\vec{a}-\vec{b}+3\vec{c}}{|2\vec{a}-\vec{b}+3\vec{c}|}\)\(=\frac{3i^-3\hat{j}+2\hat{k}}{\sqrt{22}}=\frac{3}{\sqrt{22}}\hat{i}-\frac{3}{\sqrt{22}}\hat{j}+\frac{2}{\sqrt{22}}\hat{k}\).
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
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(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
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