\(2 + \sqrt{2}\)
To solve the equation \(2 \tan^2 \theta - 4 \sec \theta + 3 = 0\), substitute \(\sec \theta\) with \(\frac{1}{\cos \theta}\) and \(\tan^2 \theta\) with \(\sec^2 \theta - 1\) to obtain: \[ 2(\sec^2 \theta - 1) - 4 \sec \theta + 3 = 0 \] Simplifying, we have: \[ 2 \sec^2 \theta - 4 \sec \theta + 1 = 0 \] Let \(x = \sec \theta\). The equation becomes: \[ 2x^2 - 4x + 1 = 0 \] Using the quadratic formula, \(x = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a}\), where \(a = 2\), \(b = -4\), and \(c = 1\): \[ x = \frac{4 \pm \sqrt{(-4)^2 - 4 \times 2 \times 1}}{2 \times 2} \] \[ x = \frac{4 \pm \sqrt{16 - 8}}{4} \] \[ x = \frac{4 \pm \sqrt{8}}{4} \] \[ x = \frac{4 \pm 2\sqrt{2}}{4} \] \[ x = 1 \pm \frac{\sqrt{2}}{2} \] Thus, \(x = 1 + \frac{\sqrt{2}}{2}\) or \(x = 1 - \frac{\sqrt{2}}{2}\), translating to \(\sec \theta = 1 + \frac{\sqrt{2}}{2}\) or \(\sec \theta = 1 - \frac{\sqrt{2}}{2}\). For \(2 \sec \theta\), we get: \[ 2 \sec \theta = 2 + \sqrt{2} \quad \text{or} \quad 2 \sec \theta = 2 - \sqrt{2} \] Since \(\theta\) is an acute angle, we choose the positive value: \[ 2 \sec \theta = 2 + \sqrt{2} \]
Observe the following data given in the table. (\(K_H\) = Henry's law constant)
| Gas | CO₂ | Ar | HCHO | CH₄ |
|---|---|---|---|---|
| \(K_H\) (k bar at 298 K) | 1.67 | 40.3 | \(1.83 \times 10^{-5}\) | 0.413 |
The correct order of their solubility in water is
For a first order decomposition of a certain reaction, rate constant is given by the equation
\(\log k(s⁻¹) = 7.14 - \frac{1 \times 10^4 K}{T}\). The activation energy of the reaction (in kJ mol⁻¹) is (\(R = 8.3 J K⁻¹ mol⁻¹\))
Note: The provided value for R is 8.3. We will use the more precise value R=8.314 J K⁻¹ mol⁻¹ for accuracy, as is standard.