In the first step, the reaction of bromobenzene (\( C_6H_5Br \)) with methyl bromide (\( CH_3Br \)) in the presence of alcoholic NaOH undergoes a nucleophilic substitution to form B, which is ortho-bromophenol.
In the second step, treating ortho-bromophenol with \( \text{HBr} \) in ether leads to the formation of C, which is para-bromophenol.
Compound A (bromobenzene) and compound C (para-bromophenol) are position isomers because they differ in the position of the bromine and hydroxyl groups on the benzene ring.
The structures of B and C are as shown in Option (3), and A and C are position isomers.
Consider the following half cell reaction $ \text{Cr}_2\text{O}_7^{2-} (\text{aq}) + 6\text{e}^- + 14\text{H}^+ (\text{aq}) \longrightarrow 2\text{Cr}^{3+} (\text{aq}) + 7\text{H}_2\text{O}(1) $
The reaction was conducted with the ratio of $\frac{[\text{Cr}^{3+}]^2}{[\text{Cr}_2\text{O}_7^{2-}]} = 10^{-6}$
The pH value at which the EMF of the half cell will become zero is ____ (nearest integer value)
[Given : standard half cell reduction potential $\text{E}^\circ_{\text{Cr}_2\text{O}_7^{2-}, \text{H}^+/\text{Cr}^{3+}} = 1.33\text{V}, \quad \frac{2.303\text{RT}}{\text{F}} = 0.059\text{V}$
20 mL of sodium iodide solution gave 4.74 g silver iodide when treated with excess of silver nitrate solution. The molarity of the sodium iodide solution is _____ M. (Nearest Integer value) (Given : Na = 23, I = 127, Ag = 108, N = 14, O = 16 g mol$^{-1}$)