Highest enol content will be shown by:
The Correct Option is A
Solution and Explanation
Option 1 has the highest enol content because it allows the formation of a stable, conjugated keto-enol tautomerization that is favoured by resonance in aromatic systems.
Top Questions on Alcohols, Phenols and Ethers
The order of acidity of the following compounds is:
(i) o-Nitrophenol
(ii) Phenol
(iii) o-Cresol
(iv) Ethanol- KEAM - 2025
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- Alcohols, Phenols and Ethers
- Acetanilide is prepared by reacting -------and-------.
- KEAM - 2025
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- Alcohols, Phenols and Ethers
Given below are two statements:
Statement I: Dimethyl ether is completely soluble in water. However, diethyl ether is soluble in water to a very small extent.
Statement II: Sodium metal can be used to dry diethyl ether and not ethyl alcohol.
In the light of the given statements, choose the correct answer from the options given below:- JEE Main - 2025
- Chemistry
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- With excess bromine, phenol reacts to form
- AIIMS BSc Nursing - 2024
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- In the following reaction sequence, the major product P is formed.
Glycerol reacts completely with excess P in the presence of an acid catalyst to form Q. Reaction of Q with excess NaOH followed by the treatment with CaCl2 yields Ca-soap R, quantitatively. Starting with one mole of Q, the amount of R produced in gram is ______.
[Given, atomic weight: H = 1, C = 12, N = 14, O = 16, Na = 23, Cl = 35, Ca = 40]- JEE Advanced - 2024
- Chemistry
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Questions Asked in JEE Main exam
Let A be a 3 × 3 matrix such that \(\text{det}(A) = 5\). If \(\text{det}(3 \, \text{adj}(2A)) = 2^{\alpha \cdot 3^{\beta} \cdot 5^{\gamma}}\), then \( (\alpha + \beta + \gamma) \) is equal to:
- JEE Main - 2025
- Matrix Operations
- Let \( P_n = \alpha^n + \beta^n \), \( P_{10} = 123 \), \( P_9 = 76 \), \( P_8 = 47 \), and \( P_1 = 1 \). The quadratic equation whose roots are \( \frac{1}{\alpha} \) and \( \frac{1}{\beta} \) is:
- JEE Main - 2025
- Sequences and Series
- Number of functions \( f: \{1, 2, \dots, 100\} \to \{0, 1\} \), that assign 1 to exactly one of the positive integers less than or equal to 98, is equal to:
- JEE Main - 2025
- Vectors
- Three infinitely long wires with linear charge density \( \lambda \) are placed along the x-axis, y-axis and z-axis respectively. Which of the following denotes an equipotential surface?
- JEE Main - 2025
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- The number of 6-letter words, with or without meaning, that can be formed using the letters of the word "MATHS" such that any letter that appears in the word must appear at least twice is:
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Concepts Used:
Preparation - Alcohols, Phenols and Ethers
Alcohols, phenols, and ethers are organic compounds that can be prepared by various methods.
Preparation of Alcohols:
- Direct hydration of alkenes: Alcohols can be prepared by the addition of water to an alkene in the presence of a strong acid catalyst.
- Reduction of carbonyl compounds: Alcohols can be prepared by the reduction of aldehydes, ketones, or carboxylic acids using reducing agents like NaBH4 or LiAlH4.
- Grignard reaction: Alcohols can be prepared by reacting Grignard reagents with carbonyl compounds.
- Hydroboration-oxidation: Alcohols can be prepared by the hydroboration of alkenes followed by oxidation with an oxidizing agent like H2O2.
Preparation of Phenols:
- Hydrolysis of diazonium salts: Phenols can be prepared by the hydrolysis of diazonium salts, which are formed by the reaction of aniline with nitrous acid.
- Oxidation of sulfonic acids: Phenols can be prepared by the oxidation of sulfonic acids using strong oxidizing agents like potassium permanganate or chromic acid.
Preparation of Ethers:
- Williamson synthesis: Ethers can be prepared by the reaction of an alkoxide ion with a primary alkyl halide or tosylate in the presence of a strong base like NaOH or KOH.
- Dehydration of alcohols: Ethers can be prepared by the dehydration of alcohols in the presence of a strong acid catalyst like H2SO4.
In summary, alcohols, phenols, and ethers can be prepared by a variety of methods, including hydration, reduction, Grignard reaction, hydroboration-oxidation, hydrolysis, oxidation, Williamson synthesis, and dehydration. The choice of the method depends on the availability of starting materials, the desired product, and the conditions of the reaction.